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Issue 44, 2020
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Direct synthesis of novel quinoxaline derivatives via palladium-catalyzed reductive annulation of catechols and nitroarylamines

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Abstract

Here, a palladium-catalyzed new hydrogenative annulation reaction of catechols and nitroarylamines, allowing straightforward access to two classes of novel quinoxaline derivatives, is reported. The reaction proceeds with operational simplicity, an easily available catalyst system, and a broad substrate scope, and without the need for pre-functionalization, which offers the potential for further design of new reductive transformations of renewable resources into value-added products.

Graphical abstract: Direct synthesis of novel quinoxaline derivatives via palladium-catalyzed reductive annulation of catechols and nitroarylamines

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Submitted
12 Dec 2019
Accepted
20 Apr 2020
First published
20 Apr 2020

Chem. Commun., 2020,56, 5997-6000
Article type
Communication

Direct synthesis of novel quinoxaline derivatives via palladium-catalyzed reductive annulation of catechols and nitroarylamines

F. Xie, Y. Li, X. Chen, L. Chen, Z. Zhu, B. Li, Y. Huang, K. Zhang and M. Zhang, Chem. Commun., 2020, 56, 5997
DOI: 10.1039/C9CC09649C

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