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Issue 25, 2020
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Validation of the inverted adsorption structure for free-base tetraphenyl porphyrin on Cu(111)

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Abstract

Utilising normal incidence X-ray standing waves we rigourously scrutinise the “inverted model” as the adsorption structure of free-base tetraphenyl porphyrin on Cu(111). We demonstrate that the iminic N atoms are anchored at near-bridge adsorption sites on the surface displaced laterally by 1.1 ± 0.2 Å in excellent agreement with previously published calculations.

Graphical abstract: Validation of the inverted adsorption structure for free-base tetraphenyl porphyrin on Cu(111)

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Article information


Submitted
12 Dec 2019
Accepted
28 Jan 2020
First published
02 Mar 2020

This article is Open Access

Chem. Commun., 2020,56, 3681-3684
Article type
Communication

Validation of the inverted adsorption structure for free-base tetraphenyl porphyrin on Cu(111)

P. T. P. Ryan, P. L. Lalaguna, F. Haag, M. M. Braim, P. Ding, D. J. Payne, J. V. Barth, T.-L. Lee, D. P. Woodruff, F. Allegretti and D. A. Duncan, Chem. Commun., 2020, 56, 3681
DOI: 10.1039/C9CC09638H

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