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Spin transition in a ferrous chloride complex supported by a pentapyridine ligand

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Abstract

Ferrous chloride complexes [FeIILxCl] commonly attain a high-spin state independently of the supporting ligand(s) and temperature. Herein, we present the first report of a complete spin crossover with T1/2 = 80 K in [FeII(Py5OH)Cl]+ (Py5OH = pyridine-2,6-diylbis[di(pyridin-2-yl)methanol]). Both spin forms of the complex are analyzed by X-ray spectroscopy and DFT calculations.

Graphical abstract: Spin transition in a ferrous chloride complex supported by a pentapyridine ligand

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Article information


Submitted
11 Dec 2019
Accepted
05 Feb 2020
First published
05 Feb 2020

This article is Open Access

Chem. Commun., 2020, Advance Article
Article type
Communication

Spin transition in a ferrous chloride complex supported by a pentapyridine ligand

M. Boniolo, S. I. Shylin, P. Chernev, M. H. Cheah, P. A. Heizmann, P. Huang, N. Salhi, K. Hossain, A. Thapper, M. Lundberg and J. Messinger, Chem. Commun., 2020, Advance Article , DOI: 10.1039/C9CC09630B

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