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Issue 14, 2020
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Tracing and elucidating visible-light mediated oxidation and C–H functionalization of amines using mass spectrometry

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Abstract

The co-existing mechanism of visible light mediated direct oxidation and C–H functionalization of amines was investigated by capturing all the intermediates using online mass spectrometry. The two-step dehydrogenation of amine involving a proton coupled electron transfer (PCET) process was revealed for the first time.

Graphical abstract: Tracing and elucidating visible-light mediated oxidation and C–H functionalization of amines using mass spectrometry

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Article information


Submitted
11 Dec 2019
Accepted
14 Jan 2020
First published
16 Jan 2020

Chem. Commun., 2020,56, 2163-2166
Article type
Communication

Tracing and elucidating visible-light mediated oxidation and C–H functionalization of amines using mass spectrometry

W. Ai, Y. Gao, J. Xue, X. Liu, H. Liu, J. Wang and Y. Bai, Chem. Commun., 2020, 56, 2163
DOI: 10.1039/C9CC09629A

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