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Copper-catalyzed non-directed hydrosilylation of cyclopropenes: highly diastereoselective synthesis of fully substituted cyclopropylsilanes

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Abstract

The non-directed hydrosilylation of cyclopropenes with earth-abundant and environmentally benign base metal catalysis was described. This protocol is effective for a wide array of 3,3-disubstituted and 1,2-disubstituted cyclopropenes, and hence provides a facile and straightforward route to synthetically valuable polysubstituted and challenging fully substituted cyclopropylsilanes with high efficiency and diastereoselectivity.

Graphical abstract: Copper-catalyzed non-directed hydrosilylation of cyclopropenes: highly diastereoselective synthesis of fully substituted cyclopropylsilanes

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Article information


Submitted
11 Dec 2019
Accepted
09 Jan 2020
First published
09 Jan 2020

Chem. Commun., 2020, Advance Article
Article type
Communication

Copper-catalyzed non-directed hydrosilylation of cyclopropenes: highly diastereoselective synthesis of fully substituted cyclopropylsilanes

H. Wang, G. Zhang, Q. Zhang, Y. Wang, Y. Li, T. Xiong and Q. Zhang, Chem. Commun., 2020, Advance Article , DOI: 10.1039/C9CC09584E

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