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Photocatalytic and electrocatalytic hydrogen production using nickel complexes supported by hemilabile and non-innocent ligands

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Abstract

Nickel complexes with non-innocent ligands generated by one-electron reduction of octahedral Schiff base nickel(II) complexes with hemilabile ligands exhibited excellent catalytic activities of over 5000 TONs through a metal–ligand cooperation mechanism for hydrogen evolution from water under visible light irradiation.

Graphical abstract: Photocatalytic and electrocatalytic hydrogen production using nickel complexes supported by hemilabile and non-innocent ligands

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Article information


Submitted
10 Dec 2019
Accepted
10 Feb 2020
First published
12 Feb 2020

Chem. Commun., 2020, Advance Article
Article type
Communication

Photocatalytic and electrocatalytic hydrogen production using nickel complexes supported by hemilabile and non-innocent ligands

S. Inoue, Y. Yan, K. Yamanishi, Y. Kataoka and T. Kawamoto, Chem. Commun., 2020, Advance Article , DOI: 10.1039/C9CC09568C

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