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A general and green fluoroalkylation reaction promoted via noncovalent interactions between acetone and fluoroalkyl iodides

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Abstract

The first example of visible light promoted fluoroalkylation reactions initiated via noncovalent interactions between acetone and fluoroalkyl iodides is presented. The reaction system features synthetic simplicity, mild reaction conditions without any photoredox catalyst, and high functional group tolerance. A wide range of substrate scopes such as alkenes, alkynes and (hetero)arenes were all compatible with the reaction system.

Graphical abstract: A general and green fluoroalkylation reaction promoted via noncovalent interactions between acetone and fluoroalkyl iodides

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Article information


Submitted
07 Dec 2019
Accepted
09 Jan 2020
First published
09 Jan 2020

Chem. Commun., 2020, Advance Article
Article type
Communication

A general and green fluoroalkylation reaction promoted via noncovalent interactions between acetone and fluoroalkyl iodides

T. Mao, M. Ma, L. Zhao, D. Xue, Y. Yu, J. Gu and C. He, Chem. Commun., 2020, Advance Article , DOI: 10.1039/C9CC09517A

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