Jump to main content
Jump to site search

Issue 9, 2020
Previous Article Next Article

A phosphoryl radical-initiated Atherton–Todd-type reaction under open air

Author affiliations

Abstract

A phosphoryl radical-initiated Atherton–Todd-type reaction using air as the radical initiator and CHCl3 as the halogenating reagent for the phosphorylation of alcohols, phenols, and amines has been developed. This novel transformation provides a highly efficient route to important phosphinates, phosphinic amides, and phosphoramidates in up to 99% yield with a broad substrate scope under very mild conditions (48 examples).

Graphical abstract: A phosphoryl radical-initiated Atherton–Todd-type reaction under open air

Back to tab navigation

Supplementary files

Article information


Submitted
04 Dec 2019
Accepted
20 Dec 2019
First published
20 Dec 2019

Chem. Commun., 2020,56, 1357-1360
Article type
Communication

A phosphoryl radical-initiated Atherton–Todd-type reaction under open air

Y. Ou, Y. Huang, Z. He, G. Yu, Y. Huo, X. Li, Y. Gao and Q. Chen, Chem. Commun., 2020, 56, 1357
DOI: 10.1039/C9CC09407E

Social activity

Search articles by author

Spotlight

Advertisements