Jump to main content
Jump to site search


Acid promoted radical-chain difunctionalization of styrenes with stabilized radicals and (N,O)-nucleophiles

Author affiliations

Abstract

A difunctionalization of alkenes through sequential addition of a radical and a nucleophile has been developed, which is suggested to proceed by a radical chain mechanism not requiring a catalyst. An electron transfer step to the oxidant benzoyl peroxide is facilitated by protonation with a strong acid.

Graphical abstract: Acid promoted radical-chain difunctionalization of styrenes with stabilized radicals and (N,O)-nucleophiles

Back to tab navigation

Supplementary files

Article information


Submitted
02 Dec 2019
Accepted
07 Jan 2020
First published
07 Jan 2020

This article is Open Access

Chem. Commun., 2020, Advance Article
Article type
Communication

Acid promoted radical-chain difunctionalization of styrenes with stabilized radicals and (N,O)-nucleophiles

S. Liu and M. Klussmann, Chem. Commun., 2020, Advance Article , DOI: 10.1039/C9CC09369A

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Material from this article can be used in other publications provided that the correct acknowledgement is given with the reproduced material.

Reproduced material should be attributed as follows:

  • For reproduction of material from NJC:
    [Original citation] - Published by The Royal Society of Chemistry (RSC) on behalf of the Centre National de la Recherche Scientifique (CNRS) and the RSC.
  • For reproduction of material from PCCP:
    [Original citation] - Published by the PCCP Owner Societies.
  • For reproduction of material from PPS:
    [Original citation] - Published by The Royal Society of Chemistry (RSC) on behalf of the European Society for Photobiology, the European Photochemistry Association, and RSC.
  • For reproduction of material from all other RSC journals:
    [Original citation] - Published by The Royal Society of Chemistry.

Information about reproducing material from RSC articles with different licences is available on our Permission Requests page.


Social activity

Search articles by author

Spotlight

Advertisements