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One simple Ir/hydrosilane catalytic system for chemoselective isomerization of 2-substituted allylic ethers

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Abstract

Here, we describe one simple Ir/hydrosilane catalytic system for chemoselective isomerization of 2-substituted allylic ethers. This facile strategy shows high efficiency towards a variety of substrates, including derivatives from bioactive molecules. The substituent at the α position of the olefins is supposed to be critical in retarding the alkene hydrosilylation process and leading the reaction to go through the isomerization pathway.

Graphical abstract: One simple Ir/hydrosilane catalytic system for chemoselective isomerization of 2-substituted allylic ethers

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Article information


Submitted
21 Nov 2019
Accepted
10 Jan 2020
First published
14 Jan 2020

Chem. Commun., 2020, Advance Article
Article type
Communication

One simple Ir/hydrosilane catalytic system for chemoselective isomerization of 2-substituted allylic ethers

W. Gao, X. Zhang, X. Xie and S. Ding, Chem. Commun., 2020, Advance Article , DOI: 10.1039/C9CC09055J

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