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Copper mediated C(sp2)–H amination and hydroxylation of phosphinamides

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Abstract

Copper mediated C(sp2)–H amination and hydroxylation of arylphosphinic acid are accomplished by adopting phosphinamide as the directing group. This method is distinguished by its wide substrate scope and excellent functional group tolerance, thus allowing for the rapid preparation of organophosphorus compounds in organic synthesis.

Graphical abstract: Copper mediated C(sp2)–H amination and hydroxylation of phosphinamides

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Article information


Submitted
13 Nov 2019
Accepted
20 Dec 2019
First published
21 Dec 2019

Chem. Commun., 2020, Advance Article
Article type
Communication

Copper mediated C(sp2)–H amination and hydroxylation of phosphinamides

S. Sun, M. Shang, H. Xu, T. Cheng, M. Li and H. Dai, Chem. Commun., 2020, Advance Article , DOI: 10.1039/C9CC08879B

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