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Transition metal-free cyclobutene rearrangement in fused naphthalen-1-ones: controlled access to functionalized quinones

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Abstract

The controlled synthesis of 1,4-naphthoquinones and tetraphene-7,12-diones, which bear the ABCD-ring of landomycins, has been accomplished directly through oxidative rearrangement of common stable precursors, namely, previously non-isolable cyclobuta[a]naphthalen-4(2H)-ones.

Graphical abstract: Transition metal-free cyclobutene rearrangement in fused naphthalen-1-ones: controlled access to functionalized quinones

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Submitted
05 Nov 2019
Accepted
19 Dec 2019
First published
19 Dec 2019

This article is Open Access

Chem. Commun., 2020, Advance Article
Article type
Communication

Transition metal-free cyclobutene rearrangement in fused naphthalen-1-ones: controlled access to functionalized quinones

F. Herrera, A. Luna, I. Fernández and P. Almendros, Chem. Commun., 2020, Advance Article , DOI: 10.1039/C9CC08628E

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