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Synthesis of 2-alkenylfurans via a Ag(i)-catalyzed tandem cyclization/cross-coupling reaction of enynones with iodonium ylides

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Abstract

A silver(I)-catalyzed tandem cyclization/cross-coupling reaction of enynones with iodonium ylides to construct carbon–carbon double bonds has been developed. The strategy provides a novel method for the synthesis of 2-alkenylfurans. This is the first cross-coupling reaction between metal–carbene complexes and iodonium ylides.

Graphical abstract: Synthesis of 2-alkenylfurans via a Ag(i)-catalyzed tandem cyclization/cross-coupling reaction of enynones with iodonium ylides

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Article information


Submitted
02 Nov 2019
Accepted
19 Dec 2019
First published
20 Dec 2019

Chem. Commun., 2020, Advance Article
Article type
Communication

Synthesis of 2-alkenylfurans via a Ag(I)-catalyzed tandem cyclization/cross-coupling reaction of enynones with iodonium ylides

H. Peng, Y. Wan, Y. Zhang and G. Deng, Chem. Commun., 2020, Advance Article , DOI: 10.1039/C9CC08561K

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