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Janus bis(NHCs) tuned by heteroatom-bridge oxidation states

Abstract

Synthesis of the first tricyclic bis(carbenes) with facially opposed imidazole-2-ylidenes and two linking phosphorus centres in different oxidation states is presented using a modular, high-yield synthetic route. The formation of homo bimetallic coinage metal complexes provides a glimpse on their potential use.

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Article information


Submitted
30 Oct 2019
Accepted
13 Jan 2020
First published
13 Jan 2020

Chem. Commun., 2020, Accepted Manuscript
Article type
Communication

Janus bis(NHCs) tuned by heteroatom-bridge oxidation states

N. R. Naz, G. Schnakenburg, A. Mikeházi, Z. Kelemen, L. Nyulaszi, R. Boeré and R. Streubel , Chem. Commun., 2020, Accepted Manuscript , DOI: 10.1039/C9CC08468A

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