Janus bis(NHCs) tuned by heteroatom-bridge oxidation states

Nabila Rauf Naz; Gregor Schnakenburg; Antal Mikeházi; Zsolt Kelemen; László Nyulászi; René T. Boeré; Rainer Streubel

doi:10.1039/C9CC08468A

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Janus bis(NHCs) tuned by heteroatom-bridge oxidation states†

Nabila Rauf Naz,^a Gregor Schnakenburg,

^a Antal Mikeházi,

^b Zsolt Kelemen,

^b László Nyulászi,

*^b René T. Boeré

^c and Rainer Streubel

*^a

Author affiliations

* Corresponding authors

^a Institut für Anorganische Chemie der Rheinischen Friedrich-Wilhelms-Universität Bonn, Gerhard-Domagk-Strasse 1, 53121 Bonn, Germany
E-mail: r.streubel@uni-bonn.de
Web: http://anorganik.chemie.uni-bonn.de/akstreubel

^b Department of Inorganic and Analytical Chemistry and MTA-BME Computation Driven Chemistry Research Group, Budapest University of Technology and Economics, Szt Gellert ter 4, 1111 Budapest, Hungary
E-mail: nyulaszi@mail.bme.hu

^c Department of Chemistry and Biochemistry, University of Lethbridge, 4401 University Drive West, Lethbridge, AB, Canada
E-mail: boere@uleth.ca

Abstract

Synthesis of the first tricyclic bis(carbenes) with facially opposed imidazole-2-ylidenes and two linking phosphorus centres in different oxidation states is presented using a modular, high-yield synthetic route. The formation of homo bimetallic coinage metal complexes provides a glimpse on their potential use.

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Supplementary files

Crystal structure data CIF (4344K)

Article information

DOI: https://doi.org/10.1039/C9CC08468A
Article type: Communication
Submitted: 30 Oct 2019
Accepted: 13 Jan 2020
First published: 13 Jan 2020
This article is Open Access

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Chem. Commun., 2020,56, 2646-2649

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Janus bis(NHCs) tuned by heteroatom-bridge oxidation states

N. R. Naz, G. Schnakenburg, A. Mikeházi, Z. Kelemen, L. Nyulászi, R. T. Boeré and R. Streubel, Chem. Commun., 2020, 56, 2646 DOI: 10.1039/C9CC08468A

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Chemical Communications

Janus bis(NHCs) tuned by heteroatom-bridge oxidation states†

Abstract

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Janus bis(NHCs) tuned by heteroatom-bridge oxidation states

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