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1,3,5-Triazine and dibenzo[b,d]thiophene sulfone based conjugated porous polymers for highly efficient photocatalytic hydrogen evolution

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Abstract

Organic conjugated porous polymers, triazine-Ph-CPP and triazine-Th-CPP, are synthesized and characterized. Without further addition of co-catalysts, triazine-Ph-CPP exhibits a HER of 16 287 μmol g−1 h−1 and an apparent quantum yield of 61.5% at 365 nm, which demonstrates that the dibenzo[b,d]thiophene sulfone and 1,3,5-triazine based polymer is a unique prototype of a highly efficient hydrogen evolution photocatalyst.

Graphical abstract: 1,3,5-Triazine and dibenzo[b,d]thiophene sulfone based conjugated porous polymers for highly efficient photocatalytic hydrogen evolution

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Article information


Submitted
28 Oct 2019
Accepted
07 Jan 2020
First published
07 Jan 2020

Chem. Commun., 2020, Advance Article
Article type
Communication

1,3,5-Triazine and dibenzo[b,d]thiophene sulfone based conjugated porous polymers for highly efficient photocatalytic hydrogen evolution

J. Wang, G. Ouyang, Y. Wang, X. Qiao, W. Li and H. Li, Chem. Commun., 2020, Advance Article , DOI: 10.1039/C9CC08412F

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