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A hydrophobic semiconducting metal–organic framework assembled from silver chalcogenide wires

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Abstract

Silver chalcogenide wires are assembled for the first time using a linear fluorinated carboxylate ligand into a metal–organic framework (MOF) with multifunctional properties. Fluorinated ligands in the host framework endow the MOF with excellent hydrophobicity. More interestingly, it displays typical semiconductivity due to the ordered nanoarray of non-discrete helical (–Ag–S–)n chains.

Graphical abstract: A hydrophobic semiconducting metal–organic framework assembled from silver chalcogenide wires

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Article information


Submitted
27 Oct 2019
Accepted
09 Jan 2020
First published
10 Jan 2020

Chem. Commun., 2020, Advance Article
Article type
Communication

A hydrophobic semiconducting metal–organic framework assembled from silver chalcogenide wires

J. Wang, W. Li, Z. Wei, C. Zhang, Y. Li, X. Dong, G. Xu and S. Zang, Chem. Commun., 2020, Advance Article , DOI: 10.1039/C9CC08402A

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