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A core–shell type alkyl-Sn-oxo cluster of {Sn14As16} bridged by 4-aminophenylarsonate ligands and incorporated with a {Na6} cluster

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Abstract

Herein, we report the largest organotin-oxo arsonate cluster {Sn14As16}, which is made up of a tetramer of alkyl-Sn-oxo subunits linked by four APA ligands and incorporated with a zigzag belt-like {Na6} cluster. This complex shows high water stability and finds potential application as an electrode decoration material in CO2 reduction.

Graphical abstract: A core–shell type alkyl-Sn-oxo cluster of {Sn14As16} bridged by 4-aminophenylarsonate ligands and incorporated with a {Na6} cluster

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Article information


Submitted
23 Oct 2019
Accepted
20 Dec 2019
First published
21 Dec 2019

Chem. Commun., 2020, Advance Article
Article type
Communication

A core–shell type alkyl-Sn-oxo cluster of {Sn14As16} bridged by 4-aminophenylarsonate ligands and incorporated with a {Na6} cluster

Y. Zhu, J. Zhang and L. Zhang, Chem. Commun., 2020, Advance Article , DOI: 10.1039/C9CC08293J

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