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Issue 4, 2020
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Conversion of NOx1− (x = 2, 3) to NO using an oxygen-deficient polyoxovanadate–alkoxide cluster

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Abstract

We report the activation of nitrogen-containing oxyanions using an oxygen-deficient polyoxovanadate–alkoxide cluster. Reduction of NO21− and NO31− results in near-quantitative oxygen atom transfer to the coordinatively unsaturated VIII ion, and selective formation of NO. These results provide insight into possible mechanisms of oxyanion reduction by polyoxometalates.

Graphical abstract: Conversion of NOx1− (x = 2, 3) to NO using an oxygen-deficient polyoxovanadate–alkoxide cluster

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Article information


Submitted
20 Oct 2019
Accepted
04 Dec 2019
First published
05 Dec 2019

Chem. Commun., 2020,56, 555-558
Article type
Communication
Author version available

Conversion of NOx1− (x = 2, 3) to NO using an oxygen-deficient polyoxovanadate–alkoxide cluster

B. E. Petel and E. M. Matson, Chem. Commun., 2020, 56, 555
DOI: 10.1039/C9CC08230A

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