Issue 4, 2020

Conversion of NOx1− (x = 2, 3) to NO using an oxygen-deficient polyoxovanadate–alkoxide cluster

Abstract

We report the activation of nitrogen-containing oxyanions using an oxygen-deficient polyoxovanadate–alkoxide cluster. Reduction of NO21− and NO31− results in near-quantitative oxygen atom transfer to the coordinatively unsaturated VIII ion, and selective formation of NO. These results provide insight into possible mechanisms of oxyanion reduction by polyoxometalates.

Graphical abstract: Conversion of NOx1− (x = 2, 3) to NO using an oxygen-deficient polyoxovanadate–alkoxide cluster

Supplementary files

Article information

Article type
Communication
Submitted
20 Oct 2019
Accepted
04 Dec 2019
First published
05 Dec 2019

Chem. Commun., 2020,56, 555-558

Author version available

Conversion of NOx1− (x = 2, 3) to NO using an oxygen-deficient polyoxovanadate–alkoxide cluster

B. E. Petel and E. M. Matson, Chem. Commun., 2020, 56, 555 DOI: 10.1039/C9CC08230A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements