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Issue 15, 2020
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A heterobimetallic cumulenic μ-carbido complex

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Abstract

The reaction [W(CSe)(CO)2(Tp*)]NEt4 (Tp* = hydrotris(dimethylpyrazolyl)borate) with N-methyl-N-nitroso-4-toluenesulfonamide affords the nitrosyl complex [W(CSe)(CO)(NO)(Tp*)] which on treatment with excess [Re(THF)(CO)2(η-C5H5)] affords the cumuenic μ-carbido complex [WRe(μ-C)(CO)3(NO)(Tp*)(η-C5H5)] in addition to the μ-selenido complex [Re2(μ-Se)(CO)4(η-C5H5)2].

Graphical abstract: A heterobimetallic cumulenic μ-carbido complex

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Supplementary files

Article information


Submitted
18 Oct 2019
Accepted
13 Jan 2020
First published
13 Jan 2020

Chem. Commun., 2020,56, 2356-2359
Article type
Communication

A heterobimetallic cumulenic μ-carbido complex

A. F. Hill and L. J. Watson, Chem. Commun., 2020, 56, 2356
DOI: 10.1039/C9CC08172K

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