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A Heterobimetallic Cumulenic μ-Carbido Complex

Abstract

The reaction [W(CSe)(CO)2(Tp*)]NEt4 (Tp* = hydrotris(dimethylpyrazolyl)borate) with N-methyl-N-nitroso-4-toluenesulfonamide affords the nitrosyl complex [W(CSe)(CO)(NO)(Tp*)] which on treatment with excess [Re(THF)(CO)2(η-C5H5)] affords the cumuenic μ-carbido complex [WRe(μ-C)(CO)3(NO)(Tp*)(η-C5H5)] in addition to the μ-selenido complex [Re2(μ-Se)(CO)4(η-C5H5)2].

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Article information


Submitted
18 Oct 2019
Accepted
13 Jan 2020
First published
13 Jan 2020

Chem. Commun., 2020, Accepted Manuscript
Article type
Communication

A Heterobimetallic Cumulenic μ-Carbido Complex

A. Hill and L. J. Watson, Chem. Commun., 2020, Accepted Manuscript , DOI: 10.1039/C9CC08172K

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