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Issue 1, 2020
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Mechanism of C–P bond formation via Pd-catalyzed decarbonylative phosphorylation of amides: insight into the chemistry of the second coordination sphere

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Abstract

We report on the basis of DFT computations a plausible and detailed reaction mechanism for the first Pd-catalyzed decarbonylative phosphorylation of amides forming C–P bonds, which reveals, among other things, crucial events in the second coordination sphere, including ion pair and hydrogen bonding interactions as well as proton transfer.

Graphical abstract: Mechanism of C–P bond formation via Pd-catalyzed decarbonylative phosphorylation of amides: insight into the chemistry of the second coordination sphere

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Submitted
09 Oct 2019
Accepted
23 Nov 2019
First published
25 Nov 2019

Chem. Commun., 2020,56, 113-116
Article type
Communication

Mechanism of C–P bond formation via Pd-catalyzed decarbonylative phosphorylation of amides: insight into the chemistry of the second coordination sphere

W. Tong, T. D. Ly, T. Zhao, Y. Wu and X. Wang, Chem. Commun., 2020, 56, 113
DOI: 10.1039/C9CC07923H

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