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Single-ion copper doping greatly enhances catalytic activity of manganese oxides via electronic interactions

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Abstract

Single-ion copper doping significantly improves the catalytic activity of α-MnO2 in CO oxidation, reducing the apparent activation energy to ∼0.3 eV via strong electronic interactions between the frontier orbitals of copper ions and manganese ions.

Graphical abstract: Single-ion copper doping greatly enhances catalytic activity of manganese oxides via electronic interactions

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Article information


Submitted
30 Sep 2019
Accepted
12 Dec 2019
First published
12 Dec 2019

Chem. Commun., 2020, Advance Article
Article type
Communication

Single-ion copper doping greatly enhances catalytic activity of manganese oxides via electronic interactions

X. Hu, S. Li, Y. Chen, W. Qu, J. Chen, Z. Ma and X. Tang, Chem. Commun., 2020, Advance Article , DOI: 10.1039/C9CC07669G

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