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Synthesis of planar chiral ferrocenes via a Pd(0)-catalyzed syn-carbopalladation/asymmetric C–H alkenylation process

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Abstract

The Pd(0)-catalyzed tandem intermolecular syn-carbopalladation/asymmetric C–H alkenylation reaction of N-ferrocenyl propiolamides with aryl iodides has been realized, generating planar chiral ferrocene[1,2-d] pyrrolinones in good yields. Through employing BINOL-derived phosphoramidite ligands, up to 95% ee is achieved.

Graphical abstract: Synthesis of planar chiral ferrocenes via a Pd(0)-catalyzed syn-carbopalladation/asymmetric C–H alkenylation process

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Article information


Submitted
27 Aug 2019
Accepted
02 Jan 2020
First published
04 Jan 2020

Chem. Commun., 2020, Advance Article
Article type
Communication

Synthesis of planar chiral ferrocenes via a Pd(0)-catalyzed syn-carbopalladation/asymmetric C–H alkenylation process

L. Jia, X. Liu, A. Zhang, T. Wang, Y. Hua, H. Li and L. Liu, Chem. Commun., 2020, Advance Article , DOI: 10.1039/C9CC06529F

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