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Infrared Analysis of Hair Dyeing and Bleaching History

Abstract

Forensic examination of hair is commonly performed to trace down its origin and make a connection between a suspect and a crime scene. Such examination is based on subjective microscopic analysis of hair. During the last decade, several spectroscopic approaches have been proposed to make forensic analysis of hair more robust and reliable. Surface-enhanced Raman and attenuated total internal reflection Infrared spectroscopies allowed for detection and identification of dyes directly on hair and even differentiation between commercial brands of those color-ants. However, these is a question that remains unanswered: can artificial dyes be detected on bleached hair or bleaching can be used to fully erase information about hair coloring? In this study, we report experimental results that provide a clear answer to this question. We show that Infrared analysis can be used to differentiate between undyed bleached hair and hair that was colored by both permanent and semi-permanent dyes prior to bleaching. We also show that IR can be used to distinguish between undyed unbleached and undyed bleached hair. We demonstrate that in combination with multivariate statistical analysis, IR can be used to distinguish with 96–100% accuracy between those hair classes.

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Supplementary files

Article information


Submitted
28 May 2020
Accepted
22 Jun 2020
First published
23 Jun 2020

Anal. Methods, 2020, Accepted Manuscript
Article type
Paper

Infrared Analysis of Hair Dyeing and Bleaching History

F. Contreras, A. Ermolenkov and D. Kurouski, Anal. Methods, 2020, Accepted Manuscript , DOI: 10.1039/D0AY01068E

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