Issue 31, 2020

Controlling the preferred orientation of layered BiOI solar absorbers


Bismuth oxyiodide (BiOI) has gained attention for photovoltaics, photocatalysis and photodetectors owing to its composition of non-toxic elements, tolerance to point defects, and highly-suitable optical properties. But like many other bismuth-based compounds, BiOI is a layered material with anisotropic transport properties, making control over the preferred orientation critical for achieving optimal device performance. In this work, we develop new insights into the growth mechanism of BiOI synthesized by chemical vapor deposition (CVD) and show how the preferred orientation can be controlled. By adjusting the precursor and substrate temperatures to tune whether or not we are in a nucleation- or growth-controlled regime, we reproducibly vary the ratio of the (001) and (110) orientations by over two orders of magnitude. As a result, we achieve highly c-axis oriented films, which leads to less shunting than a/b-axis oriented films, resulting in improved open-circuit voltages from a median value of 0.7 V (a/b-axis oriented) to 0.9 V (c-axis oriented) in BiOI solar cells. More broadly, the described mechanisms can be used to control the preferred orientation in other low-dimensional materials, which will be important for achieving improved performance across a wide variety of devices.

Graphical abstract: Controlling the preferred orientation of layered BiOI solar absorbers

Supplementary files

Article information

Article type
28 Apr 2020
11 Jun 2020
First published
15 Jun 2020
This article is Open Access
Creative Commons BY license

J. Mater. Chem. C, 2020,8, 10791-10797

Controlling the preferred orientation of layered BiOI solar absorbers

R. A. Jagt, T. N. Huq, K. M. Börsig, D. Sauven, L. C. Lee, J. L. MacManus-Driscoll and R. L. Z. Hoye, J. Mater. Chem. C, 2020, 8, 10791 DOI: 10.1039/D0TC02076A

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