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Issue 9, 2020
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A cubane-type manganese complex with H2O oxidation capabilities

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Abstract

We report the synthesis and characterisation of [Mn8K2O4(OH)2((CH3)3CCOO)16(CH3CN)2] whose cluster core shares some features with the oxygen evolving complex (OEC), the natural water oxidation catalyst. Importantly, this complex provides a bio-inspired complex that promotes catalytic H2O oxidation at neutral pH value.

Graphical abstract: A cubane-type manganese complex with H2O oxidation capabilities

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Article information


Submitted
06 May 2020
Accepted
23 Jun 2020
First published
24 Jun 2020

Sustainable Energy Fuels, 2020,4, 4464-4468
Article type
Communication

A cubane-type manganese complex with H2O oxidation capabilities

S. Tandon, J. Soriano-López, A. C. Kathalikkattil, G. Jin, P. Wix, M. Venkatesan, R. Lundy, M. A. Morris, G. W. Watson and W. Schmitt, Sustainable Energy Fuels, 2020, 4, 4464
DOI: 10.1039/D0SE00701C

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