Anodic SnO2 porous nanostructures with rich grain boundaries for efficient CO2 electroreduction to formate

Abstract

Formic acid (HCOOH), the acidic form of formate, is an important hydrogen carrier which can be directly used in fuel cells. Development of earth-abundant element-based catalysts to convert carbon dioxide (CO₂) into HCOOH or formate with high selectivity and high efficiency has been a vigorous research activity in recent years but remains an unsolved challenge. In this contribution, using one-step anodization, we prepare nanotubular SnO₂ porous nanostructures with high surface area (90.1 m² g⁻¹), large porosity (0.74 cm³ g⁻¹), and rich grain boundaries for electrochemical CO₂ reduction (CO₂RR). They exhibit stable 95% faradaic efficiency (FE) towards CO₂RR and 73% FE for formate at −0.8 V_RHE. The notable performance of such SnO₂ nanostructures can be attributed to their unique structural and chemical properties, which provide active sites for CO₂ adsorption and conversion, and easy access for CO₂ to the active sites. The insights gained from the structure/property relationships might be beneficial for designing superior electrocatalysts for CO₂ electroreduction into formate.