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Issue 43, 2020
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Chemical recycling of poly(thiourethane) thermosets enabled by dynamic thiourethane bonds

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Abstract

Recycling of polyurethanes is largely infeasible due to the harsh reprocessing conditions and associated risks of side reactions and degradation whereas polymer networks incorporating dynamic covalent bonds represent an attractive approach to the design of recyclable materials. Here, we report findings on the dynamic nature of thiourethanes, and their application as a new class of recyclable analogs of urethane materials. A series of small molecule experiments was initially conducted to determine the equilibrium constant and exchange reaction kinetic constant for the thiol–isocyanate reaction. Furthermore, incorporating those thiourethane moieties into a cross-linked network resulted in thermoset materials that are readily depolymerized to liquid oligomers. The resultant oligomers can be re-crosslinked to thiourethanes without any loss of performance nor change in mechanical properties (peak stress of 25 MPa with max strain of 200%). Moreover, the recycled thiol oligomers from thiourethane network polymers could potentially be transformed into other materials with mechanical properties that exceed those of the initial, pristine thiourethane materials. Overall, the ease with which these polythiourethanes are polymerized, recycled and reformulated gives a new direction and hope in the design of sustainable polymers.

Graphical abstract: Chemical recycling of poly(thiourethane) thermosets enabled by dynamic thiourethane bonds

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Article information


Submitted
22 Jul 2020
Accepted
04 Oct 2020
First published
05 Oct 2020

Polym. Chem., 2020,11, 6879-6883
Article type
Communication

Chemical recycling of poly(thiourethane) thermosets enabled by dynamic thiourethane bonds

S. Huang, M. Podgórski, X. Han and C. N. Bowman, Polym. Chem., 2020, 11, 6879
DOI: 10.1039/D0PY01050B

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