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Issue 4, 2020
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Cationic iron porphyrins with sodium dodecyl sulphate for micellar catalysis of cyclopropanation reactions

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Abstract

Here, we report that the combination of cationic iron porphyrins with sodium dodecyl sulphate (SDS) gives rise to efficient micellar catalysis of cyclopropanation reactions of styrene derivatives, using diazoacetates as carbene precursors. This simple, yet effective approach for cyclopropanations illustrates the power of micellar catalysis.

Graphical abstract: Cationic iron porphyrins with sodium dodecyl sulphate for micellar catalysis of cyclopropanation reactions

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Article information


Submitted
14 Oct 2019
Accepted
02 Jan 2020
First published
02 Jan 2020

This article is Open Access

Org. Biomol. Chem., 2020,18, 638-641
Article type
Communication

Cationic iron porphyrins with sodium dodecyl sulphate for micellar catalysis of cyclopropanation reactions

R. V. Maaskant, E. A. Polanco, R. C. W. van Lier and G. Roelfes, Org. Biomol. Chem., 2020, 18, 638
DOI: 10.1039/C9OB02223F

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