Rhodium(III)-catalysed decarboxylative C–H functionalization of isoxazoles with alkenes and sulfoxonium ylides

Somaraju Yugandar; Taiki Morita; Hiroyuki Nakamura

doi:10.1039/D0OB02027C

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Rhodium(iii)-catalysed decarboxylative C–H functionalization of isoxazoles with alkenes and sulfoxonium ylides†

Somaraju Yugandar,^a Taiki Morita^a and Hiroyuki Nakamura

*^a

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* Corresponding authors

^a Laboratory of Chemistry and Life Science, Innovative Institute of Research Tokyo Institute of Technology, 4259 Nagatsuta-cho, Midori-ku, Yokohama 226-8503, Japan
E-mail: hiro@res.titech.ac.jp

Abstract

Decarboxylative C–H functionalization of isoxazoles with electron-deficient alkenes and sulfoxonium ylides at the C5 position was achieved in the presence of rhodium(III) catalysts to give the corresponding alkenylation and acylmethylation products, respectively.

This article is part of the themed collection: Synthetic methodology in OBC

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DOI: https://doi.org/10.1039/D0OB02027C
Article type: Communication
Submitted: 04 Oct 2020
Accepted: 15 Oct 2020
First published: 20 Oct 2020

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Org. Biomol. Chem., 2020,18, 8625-8628

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Rhodium(III)-catalysed decarboxylative C–H functionalization of isoxazoles with alkenes and sulfoxonium ylides

S. Yugandar, T. Morita and H. Nakamura, Org. Biomol. Chem., 2020, 18, 8625 DOI: 10.1039/D0OB02027C

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Organic & Biomolecular Chemistry

Rhodium(iii)-catalysed decarboxylative C–H functionalization of isoxazoles with alkenes and sulfoxonium ylides†

Abstract

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Rhodium(III)-catalysed decarboxylative C–H functionalization of isoxazoles with alkenes and sulfoxonium ylides

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