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Issue 35, 2020
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Experimental and theoretical investigation of the chemical exfoliation of Cr-based MAX phase particles

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Abstract

Two-dimensional carbides/nitrides, typically called MXenes, are an emerging member of the ever-growing family of two-dimensional materials. The prediction of a ferromagnetic groundstate in chromium-containing MXenes has triggered growing interest in their chemical exfoliation from Cr-based MAX phases. However, the exfoliation poses serious difficulties using standard etching agents such as hydrofluoric acid (HF). Here, we investigate the exfoliability of Cr2GaC particles by chemical etching with aqueous HF both experimentally and theoretically. Structural and microstructural analyses show that the Cr2GaC particles decompose into chromium carbide and oxide without the formation of a Cr-based MXene. A thermodynamic analysis based on ab initio electronic structure calculations reveals that the exfoliation of Cr-based MXene from Cr2GaC by HF-etching is inhibited by more favorable competing reactions. This result confirms the experimental finding and suggests that HF is an unsuitable etching agent for a successful exfoliation of Cr2GaC.

Graphical abstract: Experimental and theoretical investigation of the chemical exfoliation of Cr-based MAX phase particles

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Supplementary files

Article information


Submitted
20 Apr 2020
Accepted
07 Jul 2020
First published
07 Jul 2020

Dalton Trans., 2020,49, 12215-12221
Article type
Paper

Experimental and theoretical investigation of the chemical exfoliation of Cr-based MAX phase particles

M. H. Tran, A. M. Malik, M. Dürrschnabel, A. Regoutz, P. Thakur, T. Lee, D. Perera, L. Molina-Luna, K. Albe, J. Rohrer and C. S. Birkel, Dalton Trans., 2020, 49, 12215
DOI: 10.1039/D0DT01448F

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