Ferrocenyl-substituted low-coordinated heavier group 14 elements

Takahiro Sasamori

doi:10.1039/D0DT01426E

Ferrocenyl-substituted low-coordinated heavier group 14 elements†

Takahiro Sasamori

Author affiliations

^a Graduate School of Science, Nagoya City University, Yamanohata 1, Mizuho-cho, Mizuho-ku, Nagoya, Aichi 467-8501, Japan
E-mail: sasamori@nsc.nagoya-cu.ac.jp

Abstract

Several examples of stable low-coordinated species of heavier group 14 elements (Si, Ge, Sb, Pb) such as divalent species and multiple-bond compounds have been reported. With the goal in mind to create unprecedented low-coordinated species of heavier group 14 elements that exhibit considerably increased redox stability, ferrocenyl (Fc)-substituted low-coordinated species of heavier group 14 elements were designed. In this short account article, recent progress on the synthesis of Fc-based low-coordinated species of heavier group 14 elements is summarized.

This article is part of the themed collection: 2020 Frontier and Perspective articles

Article information

Submitted

20 Apr 2020

Accepted

12 May 2020

First published

13 May 2020

Download Citation

Dalton Trans., 2020,49, 8029-8035

Article type

Frontier

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Ferrocenyl-substituted low-coordinated heavier group 14 elements

T. Sasamori, Dalton Trans., 2020, 49, 8029

DOI: 10.1039/D0DT01426E

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Ferrocenyl-substituted low-coordinated heavier group 14 elements†

Abstract

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Ferrocenyl-substituted low-coordinated heavier group 14 elements

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