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Issue 17, 2020
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Coinage metal tris(dialkylamido)imidophosphorane complexes as transmetallation reagents for cerium complexes

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Abstract

We report the synthesis of tetrameric Cu(I) and Ag(I) homoleptic complexes supported by the tris(piperidinyl)imidophosphorane [NP(pip)3]1− and [NP(1,2-bis-tBu-diamidoethane)(NEt2)]1− ligands. These complexes demonstrate the redox stability of the imidophosphorane ligands to oxidizing salts, and the silver complexes can, in turn, serve as oxidative transmetallation reagents for the isolation of tetravalent cerium complexes from cerium metal or trivalent cerium precursors.

Graphical abstract: Coinage metal tris(dialkylamido)imidophosphorane complexes as transmetallation reagents for cerium complexes

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Article information


Submitted
05 Mar 2020
Accepted
31 Mar 2020
First published
01 Apr 2020

Dalton Trans., 2020,49, 5420-5423
Article type
Communication

Coinage metal tris(dialkylamido)imidophosphorane complexes as transmetallation reagents for cerium complexes

L. M. Aguirre Quintana, N. Jiang, J. Bacsa and H. S. La Pierre, Dalton Trans., 2020, 49, 5420
DOI: 10.1039/D0DT00842G

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