Issue 1, 2020
From the journal:

Dalton Transactions

A spectroscopic and computational study of a tough MOF with a fragile linker: Ce-UiO-66-ADC†

Alessia Airi,a   Cesare Atzori, ORCID logo *a   Francesca Bonino, ORCID logo a   Alessandro Damin,a   Sigurd Øien-Ødegaard,b   Erlend Aunanb  and  Silvia Bordiga ORCID logo *ab  

* Corresponding authors

a Department of Chemistry, NIS and INSTM Reference Centre, University of Torino, Via G. Quarello 15, 10135 Torino, Italy
E-mail: cesare.atzori@unito.it, silvia.bordiga@unito.it

b Catalysis Section, Department of Chemistry, University of Oslo, P.O. Box 1033, N-0315 Oslo, Norway

Abstract

The thermolabile acetylene dicarboxylic acid has been introduced as linker in UiO-66 topology, synthetizing the compound with formula [Ce6O4(OH)4(ADC)6] and denoted as Ce-UiO-66-ADC MOF. The characterization by multi-technique approach coupled with computational modelling revealed a peculiar intrinsic defective nature related to the nature of the linker.

Graphical abstract: A spectroscopic and computational study of a tough MOF with a fragile linker: Ce-UiO-66-ADC

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Article information

DOI
https://doi.org/10.1039/C9DT04112E
Article type
Communication
Submitted
21 Oct 2019
Accepted
25 Nov 2019
First published
28 Nov 2019

Dalton Trans., 2020,49, 12-16

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A spectroscopic and computational study of a tough MOF with a fragile linker: Ce-UiO-66-ADC

A. Airi, C. Atzori, F. Bonino, A. Damin, S. Øien-Ødegaard, E. Aunan and S. Bordiga, Dalton Trans., 2020, 49, 12 DOI: 10.1039/C9DT04112E

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