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Issue 1, 2020
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A spectroscopic and computational study of a tough MOF with a fragile linker: Ce-UiO-66-ADC

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Abstract

The thermolabile acetylene dicarboxylic acid has been introduced as linker in UiO-66 topology, synthetizing the compound with formula [Ce6O4(OH)4(ADC)6] and denoted as Ce-UiO-66-ADC MOF. The characterization by multi-technique approach coupled with computational modelling revealed a peculiar intrinsic defective nature related to the nature of the linker.

Graphical abstract: A spectroscopic and computational study of a tough MOF with a fragile linker: Ce-UiO-66-ADC

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Article information


Submitted
21 Oct 2019
Accepted
25 Nov 2019
First published
28 Nov 2019

Dalton Trans., 2020,49, 12-16
Article type
Communication

A spectroscopic and computational study of a tough MOF with a fragile linker: Ce-UiO-66-ADC

A. Airi, C. Atzori, F. Bonino, A. Damin, S. Øien-Ødegaard, E. Aunan and S. Bordiga, Dalton Trans., 2020, 49, 12
DOI: 10.1039/C9DT04112E

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