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Issue 26, 2020
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Probing dynamics of carbon dioxide in a metal–organic framework under high pressure by high-resolution solid-state NMR

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Abstract

The application of high-resolution NMR analysis for CO2 adsorbed in a MOF under high pressure is reported for the first time. The results showed that CO2 adsorbed in MOF-74 had an unusually slow mobility (τ ∼ 10−8 s). CO2–CO2 interactions suppressed the mobility of CO2 under high pressure, which, in turn, would have contributed to the stability of CO2 at the adsorption sites.

Graphical abstract: Probing dynamics of carbon dioxide in a metal–organic framework under high pressure by high-resolution solid-state NMR

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Article information


Submitted
04 Mar 2020
Accepted
20 Apr 2020
First published
21 Apr 2020

Phys. Chem. Chem. Phys., 2020,22, 14465-14470
Article type
Paper
Author version available

Probing dynamics of carbon dioxide in a metal–organic framework under high pressure by high-resolution solid-state NMR

M. Inukai, T. Kurihara, Y. Noda, W. Jiang, K. Takegoshi, N. Ogiwara, H. Kitagawa and K. Nakamura, Phys. Chem. Chem. Phys., 2020, 22, 14465
DOI: 10.1039/D0CP01216E

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