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Issue 83, 2020
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Synthetic access to a phosphorescent non-palindromic pincer complex of palladium by a double oxidative addition – comproportionation sequence

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Abstract

A highly luminescent non-palindromic [(C^C^N)Pd] pincer complex forms upon reacting pyridine-substituted 2,2′-diiodo-biphenyl with [Pd(PPh3)4]. This case study establishes for the first time that the title compound is formed via a double oxidative addition – comproportionation sequence. DFT and TDDFT calculations complement mechanistic and photophysical characterizations.

Graphical abstract: Synthetic access to a phosphorescent non-palindromic pincer complex of palladium by a double oxidative addition – comproportionation sequence

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Supplementary files

Article information


Submitted
10 Jun 2020
Accepted
26 Aug 2020
First published
26 Aug 2020

This article is Open Access

Chem. Commun., 2020,56, 12589-12592
Article type
Communication

Synthetic access to a phosphorescent non-palindromic pincer complex of palladium by a double oxidative addition – comproportionation sequence

W. Feuerstein and F. Breher, Chem. Commun., 2020, 56, 12589
DOI: 10.1039/D0CC04065G

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