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Issue 60, 2020
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Asymmetric [N–I–N]+ halonium complexes

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Abstract

The first asymmetric halogen-bonded iodonium complexes [I(py)(4-DMAP)]PF6 (2c) and [I(py)(4-Etpy)]PF6 (2e) were prepared via [N–Ag–N]+ → [N–I–N]+ cation exchange of their analogous 2-coordinate silver complexes. The complexes were characterised by 1H and 1H–15N HMBC NMR spectroscopy, and single crystal X-ray crystallography.

Graphical abstract: Asymmetric [N–I–N]+ halonium complexes

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Supplementary files

Article information


Submitted
16 Apr 2020
Accepted
19 Jun 2020
First published
20 Jun 2020

This article is Open Access

Chem. Commun., 2020,56, 8428-8431
Article type
Communication

Asymmetric [N–I–N]+ halonium complexes

J. S. Ward, G. Fiorini, A. Frontera and K. Rissanen, Chem. Commun., 2020, 56, 8428
DOI: 10.1039/D0CC02758H

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