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Issue 27, 2020
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Pd-Catalyzed intermolecular C–H bond arylation reactions: effect of bulkiness of carboxylate ligands

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Abstract

A bulky carboxylic acid bearing one 1-adamantylmethyl and two methyl substituents at the α-position is demonstrated to work as an efficient carboxylate ligand source in Pd-catalyzed intermolecular C(sp2)–H bond arylation reactions. The reactions proceeded smoothly under mild conditions, taking advantage of the steric bulk of the carboxylate ligands.

Graphical abstract: Pd-Catalyzed intermolecular C–H bond arylation reactions: effect of bulkiness of carboxylate ligands

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Supplementary files

Article information


Submitted
12 Feb 2020
Accepted
04 Mar 2020
First published
05 Mar 2020

Chem. Commun., 2020,56, 3843-3846
Article type
Communication

Pd-Catalyzed intermolecular C–H bond arylation reactions: effect of bulkiness of carboxylate ligands

Y. Tanji, R. Hamaguchi, Y. Tsuji and T. Fujihara, Chem. Commun., 2020, 56, 3843
DOI: 10.1039/D0CC01129K

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