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Issue 87, 2020

Chemical control of photoinduced charge-transfer direction in a tetrathiafulvalene-fused dipyrrolylquinoxaline difluoroborate dyad

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Abstract

A new approach for a compact annulation of tetrathiafulvalene (TTF) and dipyrrolylquinoxaline difluoroborate (QB) is presented, leading to strong electronic interactions between the TTF and QB units. Regulation of distinct photoinduced charge flows within this dyad is achieved by external stimuli, which is also verified by TD-DFT calculations.

Graphical abstract: Chemical control of photoinduced charge-transfer direction in a tetrathiafulvalene-fused dipyrrolylquinoxaline difluoroborate dyad

Supplementary files

Article information


Submitted
24 Aug 2020
Accepted
04 Oct 2020
First published
05 Oct 2020

This article is Open Access

Chem. Commun., 2020,56, 13421-13424
Article type
Communication

Chemical control of photoinduced charge-transfer direction in a tetrathiafulvalene-fused dipyrrolylquinoxaline difluoroborate dyad

P. Zhou, U. Aschauer, S. Decurtins, T. Feurer, R. Häner and S. Liu, Chem. Commun., 2020, 56, 13421 DOI: 10.1039/D0CC05736C

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