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Issue 73, 2020
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Controlling photocatalytic reduction of CO2 in Ru(ii)/Re(i) dyads via linker oxidation state

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Abstract

Electronic communication between the linked metal centers in Ru(II)–Re(I) dyads is tuned using the oxidation state (S and SO2) of sulfur-bridged ligands. Higher catalytic activity is seen for the SO2-bridged dyad in the photocatalytic reduction of CO2.

Graphical abstract: Controlling photocatalytic reduction of CO2 in Ru(ii)/Re(i) dyads via linker oxidation state

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Article information


Submitted
02 Jul 2020
Accepted
03 Aug 2020
First published
13 Aug 2020

Chem. Commun., 2020,56, 10750-10753
Article type
Communication

Controlling photocatalytic reduction of CO2 in Ru(II)/Re(I) dyads via linker oxidation state

C. M. Brown, T. Auvray, E. E. DeLuca, M. B. Ezhova, G. S. Hanan and M. O. Wolf, Chem. Commun., 2020, 56, 10750
DOI: 10.1039/D0CC04597G

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