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Issue 74, 2020
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Thermo- and electro-switchable Cs⊂{Fe4–Fe4} cubic cage: spin-transition and electrochromism

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Abstract

A mixed valence Cs⊂{Fe4–Fe4} cyanido-cube was synthesized and structurally characterized. The molecule, which is robust in solution, shows remarkable electronic versatility. Electrochromic properties associated with nine different electronic states are observed in solution together with a thermo-induced spin-transition in the solid state.

Graphical abstract: Thermo- and electro-switchable Cs⊂{Fe4–Fe4} cubic cage: spin-transition and electrochromism

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Submitted
19 Jun 2020
Accepted
05 Aug 2020
First published
11 Aug 2020

Chem. Commun., 2020,56, 10950-10953
Article type
Communication

Thermo- and electro-switchable Cs⊂{Fe4–Fe4} cubic cage: spin-transition and electrochromism

J. Glatz, L. Chamoreau, A. Flambard, J. Meunier, A. Bousseksou and R. Lescouëzec, Chem. Commun., 2020, 56, 10950
DOI: 10.1039/D0CC04279J

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