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Issue 67, 2020
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Topology versus porosity: what can reticular chemistry tell us about free space in metal–organic frameworks?

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Abstract

We present the results of a comprehensive geometrical and topological analysis of 3D coordination networks in 33 790 coordination polymers. We have found relations between topological descriptors and free space of the networks, and have revealed topological types that promote high porosity of metal–organic frameworks.

Graphical abstract: Topology versus porosity: what can reticular chemistry tell us about free space in metal–organic frameworks?

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Article information


Submitted
08 Jun 2020
Accepted
16 Jul 2020
First published
16 Jul 2020

Chem. Commun., 2020,56, 9616-9619
Article type
Communication

Topology versus porosity: what can reticular chemistry tell us about free space in metal–organic frameworks?

A. P. Shevchenko, E. V. Alexandrov, A. A. Golov, O. A. Blatova, A. S. Duyunova and V. A. Blatov, Chem. Commun., 2020, 56, 9616
DOI: 10.1039/D0CC04004E

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