Issue 65, 2020

Hydride-encapsulated bimetallic clusters supported by 1,1-dithiolates

Abstract

Two mixed-metal hydride clusters, corresponding to x = 3 and 4, were structurally characterized from a set of atomically precise heptanuclear clusters, CuxAg7−x(H){S2P(OiPr)2}6 (x = 1–6). An interstitial hydride lying at the center of a tricapped tetrahedral cage was located and refined anisotropically by using X-ray data, and its presence acertained by multinuclear NMR spectroscopy and DFT calculations.

Graphical abstract: Hydride-encapsulated bimetallic clusters supported by 1,1-dithiolates

Supplementary files

Article information

Article type
Communication
Submitted
01 Jun 2020
Accepted
09 Jul 2020
First published
09 Jul 2020

Chem. Commun., 2020,56, 9300-9303

Hydride-encapsulated bimetallic clusters supported by 1,1-dithiolates

Y. Zhong, J. Liao, T. Chiu, Y. Wu, S. Kahlal, J. Saillard and C. W. Liu, Chem. Commun., 2020, 56, 9300 DOI: 10.1039/D0CC03848B

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