Spin crossover modulation in a coordination polymer with the redox-active bis-pyridyltetrathiafulvalene (py2TTF) ligand

Lisa Zappe; Sophie Schönfeld; Gerald Hörner; Katrina A. Zenere; Chanel F. Leong; Cameron J. Kepert; Deanna M. D'Alessandro; Birgit Weber; Suzanne M. Neville

doi:10.1039/D0CC03788E

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Spin crossover modulation in a coordination polymer with the redox-active bis-pyridyltetrathiafulvalene (py₂TTF) ligand†

Lisa Zappe,^a Sophie Schönfeld,^a Gerald Hörner,

^a Katrina A. Zenere,

^b Chanel F. Leong,^b Cameron J. Kepert,^b Deanna M. D'Alessandro,

^b Birgit Weber

*^a and Suzanne M. Neville

*^c

Author affiliations

* Corresponding authors

^a Department of Chemistry, University of Bayreuth, Universitätsstraße 30, 95448 Bayreuth, Germany
E-mail: weber@uni-bayreuth.de

^b School of Chemistry, The University of Sydney, Sydney, New South Wales, Australia

^c School of Chemistry, University of New South Wales, Sydney, NSW 2052, Australia
E-mail: s.neville@unsw.edu.au

Abstract

A one-dimensional Fe^II coordination polymer (CP) has been formed which includes the redox-active ligand bis-pyridyltetrathiafulvalene (py₂TTF) and a Schiff base-like N₂O₂ ligand. This CP is both spin crossover (SCO) and redox-active in the solid-state, and chemical oxidation results in SCO modification.

This article is part of the themed collection: Functional Coordination Networks

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Article information

DOI: https://doi.org/10.1039/D0CC03788E
Article type: Communication
Submitted: 29 May 2020
Accepted: 31 Jul 2020
First published: 07 Aug 2020

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Chem. Commun., 2020,56, 10469-10472

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Spin crossover modulation in a coordination polymer with the redox-active bis-pyridyltetrathiafulvalene (py₂TTF) ligand

L. Zappe, S. Schönfeld, G. Hörner, K. A. Zenere, C. F. Leong, C. J. Kepert, D. M. D'Alessandro, B. Weber and S. M. Neville, Chem. Commun., 2020, 56, 10469 DOI: 10.1039/D0CC03788E

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