Issue 67, 2020
From the journal:

Chemical Communications

Blue-shifted aggregation-induced enhancement of a Sn(iv) fluoride complex: the role of fluorine in luminescence enhancement†

Wooseok Ki, ORCID logo *a   Kathleen Ngo,a   Phalguni Ghosh,b   Boris Averkiev,a   Gordan T. Reeves,a   Isaiah Ailes,a   Barry C. Pemberton,a   Kun Zhuc  and  Jing Li ORCID logo c  

* Corresponding authors

a School of Natural Sciences and Mathematics, Stockton University, Galloway, USA
E-mail: Wooseok.Ki@stockton.edu
Tel: +1-609-626-5519

b Department of Natural Sciences, Middlesex County College, Edison, USA

c Department of Chemistry and Chemical Biology, Rutgers University, Piscataway, USA

Abstract

A new type of blue-shifted aggregation-induced emission enhancement was observed for a Sn(IV) fluoride complex, resulting in strong emission in the solid state as compared with that in solutions. The fluorinated Sn(IV) complex has a significantly more intense emission efficiency compared to the chlorinated Sn(IV) complex, which is attributed to stronger σ bonding.

Graphical abstract: Blue-shifted aggregation-induced enhancement of a Sn(iv) fluoride complex: the role of fluorine in luminescence enhancement

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Article information

DOI
https://doi.org/10.1039/D0CC03635H
Article type
Communication
Submitted
21 May 2020
Accepted
11 Jul 2020
First published
13 Jul 2020

Chem. Commun., 2020,56, 9648-9650

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Blue-shifted aggregation-induced enhancement of a Sn(IV) fluoride complex: the role of fluorine in luminescence enhancement

W. Ki, K. Ngo, P. Ghosh, B. Averkiev, G. T. Reeves, I. Ailes, B. C. Pemberton, K. Zhu and J. Li, Chem. Commun., 2020, 56, 9648 DOI: 10.1039/D0CC03635H

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