Jump to main content
Jump to site search

Issue 52, 2020
Previous Article Next Article

Unveiling the mechanism of hydrotropy: evidence for water-mediated aggregation of hydrotropes around the solute

Author affiliations

Abstract

A recent proposal attributes the origin of hydrotropy to the water-mediated aggregation of hydrotrope molecules around the solute. Experimental evidence for this phenomenon is reported for the first time in this work, using 1H-NMR. A new computational technique to quantify apolarity is introduced and is used to show that apolarity of both solute and hydrotrope is the driving force of hydrotropy.

Graphical abstract: Unveiling the mechanism of hydrotropy: evidence for water-mediated aggregation of hydrotropes around the solute

Back to tab navigation

Supplementary files

Article information


Submitted
05 May 2020
Accepted
21 May 2020
First published
21 May 2020

Chem. Commun., 2020,56, 7143-7146
Article type
Communication

Unveiling the mechanism of hydrotropy: evidence for water-mediated aggregation of hydrotropes around the solute

D. O. Abranches, J. Benfica, B. P. Soares, A. Leal-Duaso, T. E. Sintra, E. Pires, S. P. Pinho, S. Shimizu and J. A. P. Coutinho, Chem. Commun., 2020, 56, 7143
DOI: 10.1039/D0CC03217D

Social activity

Search articles by author

Spotlight

Advertisements