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Issue 69, 2020

Red light-triggered photoreduction on a nucleic acid template

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Abstract

Conjugate Sn(IV)(pyropheophorbide a)dichloride–(peptide nucleic acid) catalyzes reduction of azobenzene derivatives in the presence of complementary nucleic acid (NA) upon irridiation with red light (660 nm). This is the first red light-induced NA-templated photoreduction. It is highly sensitive to single mismatches in the NA-template and can detect down to 5 nM NAs.

Graphical abstract: Red light-triggered photoreduction on a nucleic acid template

Supplementary files

Article information


Submitted
30 Apr 2020
Accepted
22 Jul 2020
First published
22 Jul 2020

Chem. Commun., 2020,56, 10026-10029
Article type
Communication

Red light-triggered photoreduction on a nucleic acid template

S. Dutta, J. Rühle, M. Schikora, N. Deussner-Helfmann, M. Heilemann, T. Zatsepin, P. Duchstein, D. Zahn, G. Knör and A. Mokhir, Chem. Commun., 2020, 56, 10026 DOI: 10.1039/D0CC03086D

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