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Issue 32, 2020
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Valence tautomerism in a cobalt-verdazyl coordination compound

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Abstract

Coordination of 1-isopropyl-3,5-dipyridyl-6-oxoverdazyl to cobalt results in a dication best described in the solid state as a high spin cobalt(II) ion coordinated to two radical ligands with an S = 3/2 ground state. On dissolution in acetonitrile, the cobalt(II) form equilibrates with a cobalt(III) valence tautomer with an S = 1/2 ground state.

Graphical abstract: Valence tautomerism in a cobalt-verdazyl coordination compound

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Article information


Submitted
06 Mar 2020
Accepted
26 Mar 2020
First published
26 Mar 2020

Chem. Commun., 2020,56, 4400-4403
Article type
Communication

Valence tautomerism in a cobalt-verdazyl coordination compound

C. Fleming, D. Chung, S. Ponce, D. J. R. Brook, J. DaRos, R. Das, A. Ozarowski and S. A. Stoian, Chem. Commun., 2020, 56, 4400
DOI: 10.1039/D0CC01770A

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