Issue 40, 2020

A heterodinuclear, formal Au+IPt0 complex with weakly bound alkene ligands

Abstract

[(Ph3P)AuPt(nbe)3][BAr4F] (nbe = norbornene) constitutes the first olefin-containing, formal Au+IPt0 complex. The unusual coordination mode and the electronic properties have been analyzed spectroscopically and by calculations. The low binding energy of the nbe ligands make this complex a valuable precursor for formal Au+IPt0 complexes and a candidate for heterobimetallic catalysis.

Graphical abstract: A heterodinuclear, formal Au+IPt0 complex with weakly bound alkene ligands

Supplementary files

Article information

Article type
Communication
Submitted
05 Mar 2020
Accepted
02 Apr 2020
First published
02 Apr 2020

Chem. Commun., 2020,56, 5350-5353

A heterodinuclear, formal Au+IPt0 complex with weakly bound alkene ligands

L. D. Ernst, K. Koessler, A. Peter, D. Kratzert, H. Scherer and B. Butschke, Chem. Commun., 2020, 56, 5350 DOI: 10.1039/D0CC01719A

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