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Issue 40, 2020
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A heterodinuclear, formal Au+IPt0 complex with weakly bound alkene ligands

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Abstract

[(Ph3P)AuPt(nbe)3][BAr4F] (nbe = norbornene) constitutes the first olefin-containing, formal Au+IPt0 complex. The unusual coordination mode and the electronic properties have been analyzed spectroscopically and by calculations. The low binding energy of the nbe ligands make this complex a valuable precursor for formal Au+IPt0 complexes and a candidate for heterobimetallic catalysis.

Graphical abstract: A heterodinuclear, formal Au+IPt0 complex with weakly bound alkene ligands

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Article information


Submitted
05 Mar 2020
Accepted
02 Apr 2020
First published
02 Apr 2020

Chem. Commun., 2020,56, 5350-5353
Article type
Communication

A heterodinuclear, formal Au+IPt0 complex with weakly bound alkene ligands

L. D. Ernst, K. Koessler, A. Peter, D. Kratzert, H. Scherer and B. Butschke, Chem. Commun., 2020, 56, 5350
DOI: 10.1039/D0CC01719A

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