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Issue 67, 2020
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A recyclable metal–organic framework for ammonia vapour adsorption

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Abstract

Herein, we present a new strategy to design metal–organic frameworks (MOFs) as adsorbents for ammonia (NH3) vapour. The linking ligand is functionalized with a sterically hindered Lewis acidic boron (B) centre, allowing efficient capture of NH3 and easy recycling of the MOF by simply heating at low temperature. The recycled MOF material can be used for NH3 capture for at least 5 cycles without losing its crystallinity or its luminescence properties.

Graphical abstract: A recyclable metal–organic framework for ammonia vapour adsorption

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Article information


Submitted
29 Jan 2020
Accepted
17 Jul 2020
First published
17 Jul 2020

Chem. Commun., 2020,56, 9600-9603
Article type
Communication

A recyclable metal–organic framework for ammonia vapour adsorption

T. N. Nguyen, I. M. Harreschou, J. Lee, K. C. Stylianou and D. W. Stephan, Chem. Commun., 2020, 56, 9600
DOI: 10.1039/D0CC00741B

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